Footage captured by Splash News shows the Brazilian forward becoming involved in an angry dispute with his Portuguese colleague.
According to the Daily Mail, Neymar reacted harshly to a questionable challenge from Semedo, throwing some words and a shove at the right-back before Javier Mascherano came between them.
"Semedo walks away from the fiery flashpoint, but Neymar refuses to let the issue lie".
Semedo, 23, signed with Barcelona in July after transferring from Benfica.
Neymar then rips off his scrimmage vest and kicks a soccer ball in frustration.
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When Arya pronounces these words "it's not you" She means is actually that Nymeria is not the kind of she-wolf to be domesticated. She said, "Ever since the show got rid of Nymeria , it's one of the questions I've been tweeted the most".
The bust-up has served to further fuel speculation suggesting that the 25-year-old could soon be heading out of Camp Nou, with Paris Saint-Germain leading the race for his signature.
Recently, in an interview with the New York Times, the Barcelona president, Josep Bartomeu, admitted he is powerless to stop him. It is also claimed Neymar is aware that a "growing number" of supporters do not want him to stay, with recent media polls in Globo Esporte and the Barcelona-based Sport newspaper revealing that the majority of those asked think he should leave.
Sadly you can't just pack it in and storm off when we're not feeling it like a child might, but millionaire footballer Neymar can. He still has four years of his contract, so there is nothing else to say. "He believes he can be the best player in the world at another big club".
They play Real Madrid on Saturday and it is clear that his services will be very much needed. Accompanied by a member of the Barcelona staff, he leaves as training resumes without him, with the player going out into the vehicle park and leaving the training area entirely.
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